The points \(P\) and \(Q\) have position vectors \(\mathbf{a}+\mathbf{b}\) and \(3\mathbf{a}-2\mathbf{b}\) respectively relative to the origin \(O\).
Given that \(OPQR\) is a parallelogram, express the vectors \(\overrightarrow{PQ}\) and \(\overrightarrow{PR}\) in terms of \(\mathbf{a}\) and \(\mathbf{b}\).
By evaluating two scalar products, show that if \(OPQR\) is a square, then \({{\left| \mathbf{a} \right|}^{2}}=2{{\left| \mathbf{b} \right|}^{2}}\).
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