Mixing-Tank Models

Mixing-Tank Models

Assume the liquid is thoroughly mixed, so the solute concentration is uniform throughout the tank.

Quantities and units

SymbolMeaningUnits
\(V\)constant liquid volumevolume
\(x(t)\)amount of solute at time \(t\)mass
\(a\)equal volumetric inflow and outflow ratevolume per unit time
\(m\)solute inflow ratemass per unit time

The subscripts “in” and “out” denote non-negative stream rates; “net” denotes the change inside the tank. Here \(a>0\) and \(V>0\).

Liquid-volume balance

\(\begin{aligned}\left(\dfrac{\mathrm dV}{\mathrm dt}\right)_{\!\mathrm{net}}&=\left(\dfrac{\mathrm dV}{\mathrm dt}\right)_{\!\mathrm{in}}-\left(\dfrac{\mathrm dV}{\mathrm dt}\right)_{\!\mathrm{out}}\\ \dfrac{\mathrm dV}{\mathrm dt}&=a-a=0\end{aligned}\)

Concentration and solute rates

QuantityExpressionUnits
Tank concentration\(\displaystyle\frac{x(t)}{V}\)mass per volume
Solute inflow\(m\)mass per unit time
Solute outflow\(\displaystyle\frac{x(t)}{V}a\)mass per unit time

For each stream, \(\left(\dfrac{\mathrm dx}{\mathrm dV}\right)_{\!\mathrm{stream}}\) means solute mass per unit volume carried by that stream (its concentration).

\(\begin{aligned}\left(\dfrac{\mathrm dx}{\mathrm dt}\right)_{\!\mathrm{in}}&=\left(\dfrac{\mathrm dx}{\mathrm dV}\right)_{\!\mathrm{in}}\left(\dfrac{\mathrm dV}{\mathrm dt}\right)_{\!\mathrm{in}}=\dfrac{m}{a}\,a=m\\ \left(\dfrac{\mathrm dx}{\mathrm dt}\right)_{\!\mathrm{out}}&=\left(\dfrac{\mathrm dx}{\mathrm dV}\right)_{\!\mathrm{out}}\left(\dfrac{\mathrm dV}{\mathrm dt}\right)_{\!\mathrm{out}}=\dfrac{x}{V}\,a\end{aligned}\)

Apply “rate in minus rate out” separately to liquid volume and solute mass. Equal liquid flow rates keep \(V\) constant; they do not generally keep \(x\) constant.

Solute-mass balance

\(\begin{aligned}\left(\dfrac{\mathrm dx}{\mathrm dt}\right)_{\!\mathrm{net}}&=\left(\dfrac{\mathrm dx}{\mathrm dt}\right)_{\!\mathrm{in}}-\left(\dfrac{\mathrm dx}{\mathrm dt}\right)_{\!\mathrm{out}}\\ \dfrac{\mathrm dx}{\mathrm dt}&=m-\dfrac{x}{V}\,a\\ &=m-\dfrac{ax}{V}\end{aligned}\)

The coefficient \(\dfrac{a}{V}\) has units of inverse time, so \(\dfrac{a}{V}x\) has units of mass per unit time, matching \(m\) and \(\dfrac{\mathrm{d}x}{\mathrm{d}t}\).

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Answer:\(\text{Outflow mass rate}=\frac{ax}{V}\) \(\frac{\mathrm{d}x}{\mathrm{d}t}=m-\frac{ax}{V}\)

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